Unit 2.5: Covalent Bonding
Engineering Materials → Engineering Materials → Fundamentals of Engineering Materials → Fundamentals of Engineering Materials → Atomic Structure and Bonding | Author: admin | Mar 09, 2026
Introduction
Atoms combine with each other to achieve stable electronic configuration. One way atoms combine is by sharing electrons, which forms a covalent bond.
Covalent bonding generally occurs between non-metal atoms where neither atom easily loses electrons. Instead, they share electrons to complete their outer shell.
Covalent bonds are common in materials such as diamond, silicon, and many organic compounds.
Definition
Covalent bonding is the chemical bond formed when two atoms share one or more pairs of electrons to achieve stability.
Formation of Covalent Bond
Covalent bonds are formed when two atoms share their valence electrons.
Steps involved:
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Each atom contributes one or more electrons.
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The electrons are shared between the atoms.
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Sharing allows both atoms to achieve a stable outer electron shell.
Example of Covalent Bond
Hydrogen molecule (H₂)
Each hydrogen atom has 1 electron.
Two hydrogen atoms share their electrons.
H • + • H → H : H
Thus, both atoms achieve a stable configuration.
Another example:
Oxygen molecule (O₂)
Each oxygen atom has 6 valence electrons.
They share two pairs of electrons, forming a double covalent bond.
Types of Covalent Bonds
Covalent bonds may be classified based on the number of shared electron pairs.
Single bond → one pair of electrons shared
Double bond → two pairs of electrons shared
Triple bond → three pairs of electrons shared
Example:
H₂ → single bond
O₂ → double bond
N₂ → triple bond
Characteristics of Covalent Compounds
Covalent materials usually have the following properties:
Low melting and boiling points
Poor electrical conductivity
Strong directional bonds
Often exist as gases, liquids, or soft solids
However, some covalent materials like diamond are extremely hard.
Covalent Bonding in Engineering Materials
Covalent bonding is found in important engineering materials such as:
Diamond
Silicon
Germanium
These materials are used in:
Cutting tools (diamond)
Semiconductor devices (silicon)
Covalent bonding gives these materials high hardness and strong atomic bonding.
Difference Between Ionic and Covalent Bond
| Property | Ionic Bond | Covalent Bond |
|---|---|---|
| Electron behavior | Transfer of electrons | Sharing of electrons |
| Atoms involved | Metal and non-metal | Non-metals |
| Electrical conductivity | Conducts in molten state | Poor conductor |
| Bond strength | Strong electrostatic attraction | Strong shared bond |
Exam-Focused Points
Covalent bond is formed by sharing electrons.
It usually occurs between non-metal atoms.
Types of covalent bonds include single, double, and triple bonds.
Covalent materials generally show poor electrical conductivity.
Diamond is an example of strong covalent bonding.
Example Competitive Exam Questions
What is covalent bonding?
Answer — Bond formed by sharing of electrons between atoms.
Which atoms usually form covalent bonds?
Answer — Non-metal atoms.
How many electron pairs are shared in a double bond?
Answer — Two pairs.
Why are covalent compounds poor conductors of electricity?
Answer — Because they lack free electrons.
Give an example of a covalent material used in engineering.
Answer — Diamond or silicon.
Quick Revision
Covalent bonding occurs by sharing electrons.
Occurs mainly between non-metals.
Types of bonds:
Single bond
Double bond
Triple bond
Covalent materials usually have low conductivity and strong directional bonding.